Clausius-Clapeyron Boiling Point Experiment


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Testing the Clausius-Clapeyron Equation - A practical Approach

In this experiment, I aim to showcase the practical side of science, highlighting the interplay between theory and practice. In the Gas Equation section of the CHEMIX School Software, you can plot Clausius-Clapeyron pressure/boiling point curves and also calculate the boiling point at a given pressure (or vice versa). This tool enables a deeper understanding of how boiling points shift under varying pressure conditions, providing both theoretical calculations and practical demonstrations.

Comparing Theory and Practice

I conducted an experiment where I added 40°C water into a sample vial and reduced the pressure to 0.08 atm. Using a modified bike pump, I successfully demonstrated that water boils at this lower pressure. This proved the theoretical calculation of water's boiling point at low pressure, showing that the boiling point of water at 0.08 atm is indeed around 40°C.
Fig. 1: The Pump Setup Without Water
The setup consisted of the DIY vacuum extractor (modified bike pump), a pump hose, vacuum chamber, sample vial, and a check valve between the hose and the sample vial to control pressure.

vacuum extractor diy modified bike pump


Fig. 2: How to Modify a Bike Pump for Vacuum Creation
To carry out the experiment, I modified a standard bike pump so that instead of creating pressure, it generated a vacuum.

bike
        pump modification vacuum



Short Video 1
: Testing the Modified Bike Pump’s Vacuum Capabilities


Here, I tested the modified pump using a vacuum measurement tool (better referred to as a "vacuum gauge"). This demonstrated the pump’s ability to generate sufficient vacuum pressure.
The vacuum gauge shows about 50mmHg (0.066 atm) at best.


Short Video 2: The Experiment – Boiling Water at 40°C Under Low Pressure


In this video, I show that under low pressure, water boils at 40°C, demonstrating the practical aspect of the Clausius-Clapeyron relationship.


Fig.  Below: Snapshot from the CHEMIX School Software. As shown in the figure, water will boil at 40°C if the pressure is about 0.08 atm.
boling
        point curve water





Short Video 2: Boiling Water at 50°C Under Low Pressure in a Syringe.






Clausius-Clapeyron Equation Calculator & Plotter

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